Activity and Selectivity for O-2 Reduction to H2O2 on Transition Metal Surfaces

Industrially viable electrochemical production of H2O2 requires active, selective and stable electrocatalyst materials to catalyse the oxygen reduction reaction to H2O2. On the basis of density functional theory calculations, we explain why single site catalysts such as Pd/Au show improved selectivity over pure metals such as Au. </jats:p

Low-power pedestrian detection system on FPGA

Pedestrian detection is one of the key problems in the emerging self-driving car industry. In addition, the Histogram of Gradients (HOG) algorithm proved to provide good accuracy for pedestrian detection. Many research works focused on accelerating HOG algorithm on FPGA(Field-Programmable Gate Array) due to its low-power and high-throughput characteristics. In this paper, we present an energy-efficient HOG-based implementation for pedestrian detection system on a low-cost FPGA system-on-chip platform. The hardware accelerator implements the HOG computation and the Support Vector Machine classifier, the rest of the algorithm is mapped to software in the embedded processor. The hardware runs at 50 Mhz (lower frequency than previous works), thus achieving the best pixels processed per clock and the lower power design

Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper

Oxide‐derived copper (OD‐Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at −0.3 V (vs. RHE). By using static headspace‐gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD‐Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at −0.33 V (vs. RHE). We show that acetaldehyde forms at low steady‐state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification. Our results represent an important step towards understanding the CO reduction mechanism on OD‐Cu electrodes